The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil
| Main Authors: | Purnamasari, Amalia Putri, Sari, Meyga E. F., Kusumaningtyas, Desy T., Suprapto, Suprapto, Hamid, Abdul, Prasetyoko, Didik |
|---|---|
| Format: | Article info application/pdf Journal |
| Bahasa: | eng |
| Terbitan: |
Department of Chemical Engineering - Diponegoro University
, 2017
|
| Subjects: | |
| Online Access: |
https://ejournal2.undip.ac.id/index.php/bcrec/article/view/802 https://ejournal2.undip.ac.id/index.php/bcrec/article/view/802/947 https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/802/113 |
| ctrlnum |
article-802 |
|---|---|
| fullrecord |
<?xml version="1.0"?>
<dc schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"><title lang="en-US">The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil</title><creator>Purnamasari, Amalia Putri</creator><creator>Sari, Meyga E. F.</creator><creator>Kusumaningtyas, Desy T.</creator><creator>Suprapto, Suprapto</creator><creator>Hamid, Abdul</creator><creator>Prasetyoko, Didik</creator><subject lang="en-US">CaO/H-ZSM-5; Zeolite; Mesoporous; Cooking Oil; Transesterification</subject><description lang="en-US">Transesterification of used cooking oil was carried out over calcium oxide supported on mesoporous H-ZSM-5 prepared from kaolin as solid base catalysts. Solid basic catalysts investigated in this study were characterized by XRD, FTIR spectroscopy, and N2 adsorption-desorption techniques. The XRD pattern showed peaks corresponding to the CaO and mesoporous ZSM-5 in the sample. The peak intensity of the CaO increased as CaO loading in ZSM-5 was increased. The characterization based on FTIR spectroscopy revealed that CaO/H-ZSM-5 solids have functional groups characteristics of both CaO and mesoporous H-ZSM-5 which appeared in the band at around  550 cm-1 and 480 cm-1. The isotherm of N2 adsorption-desorption of CaO/H-ZSM-5 indicated the type IV isotherm with the presence of hysteresis loop. For the catalytic activity, the biodiesel yield using catalyst of 10 % CaO/HZSM-5 (100 %), 30 % CaO/HZSM-5 (100 %), 50 % CaO/HZSM-5 (100 %) were 24.34, 27.37, and 29.73 %, respectively. It also related with the basic active site, when loading CaO increased, the basic active site also increased. Copyright © 2017 BCREC Group. All rights reservedReceived: 21st November 2016; Revised: 8th March 2017; Accepted: 9th March 2017; Available online: 27th October 2017; Published regularly: December 2017How to Cite: Purnamasari, A.P., Sari, M.E.F., Kusumaningtyas, D.T., Suprapto, S., Hamid, A., Prasetyoko, D. (2017). The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil. Bulletin of Chemical Reaction Engineering & Catalysis, 12(3): 329-336 (doi:10.9767/bcrec.12.3.802.329-336) </description><publisher lang="en-US">Department of Chemical Engineering - Diponegoro University</publisher><contributor lang="en-US"/><date>2017-10-28</date><type>Journal:Article</type><type>Other:info:eu-repo/semantics/publishedVersion</type><type>Other:</type><type>File:application/pdf</type><identifier>https://ejournal2.undip.ac.id/index.php/bcrec/article/view/802</identifier><identifier>10.9767/bcrec.12.3.802.329-336</identifier><source lang="en-US">Bulletin of Chemical Reaction Engineering & Catalysis; 2017: BCREC Volume 12 Issue 3 Year 2017 (SCOPUS and Web of Science Indexed, December 2017); 329-336</source><source>1978-2993</source><language>eng</language><relation>https://ejournal2.undip.ac.id/index.php/bcrec/article/view/802/947</relation><relation>https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/802/113</relation><rights lang="en-US">Copyright (c) 2017 Bulletin of Chemical Reaction Engineering & Catalysis</rights><rights lang="en-US">http://creativecommons.org/licenses/by-sa/4.0</rights><recordID>article-802</recordID></dc>
|
| language |
eng |
| format |
Journal:Article Journal Other:info:eu-repo/semantics/publishedVersion Other Other: File:application/pdf File Journal:Journal |
| author |
Purnamasari, Amalia Putri Sari, Meyga E. F. Kusumaningtyas, Desy T. Suprapto, Suprapto Hamid, Abdul Prasetyoko, Didik |
| title |
The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil |
| publisher |
Department of Chemical Engineering - Diponegoro University |
| publishDate |
2017 |
| topic |
CaO/H-ZSM-5 Zeolite Mesoporous Cooking Oil Transesterification |
| url |
https://ejournal2.undip.ac.id/index.php/bcrec/article/view/802 https://ejournal2.undip.ac.id/index.php/bcrec/article/view/802/947 https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/802/113 |
| contents |
Transesterification of used cooking oil was carried out over calcium oxide supported on mesoporous H-ZSM-5 prepared from kaolin as solid base catalysts. Solid basic catalysts investigated in this study were characterized by XRD, FTIR spectroscopy, and N2 adsorption-desorption techniques. The XRD pattern showed peaks corresponding to the CaO and mesoporous ZSM-5 in the sample. The peak intensity of the CaO increased as CaO loading in ZSM-5 was increased. The characterization based on FTIR spectroscopy revealed that CaO/H-ZSM-5 solids have functional groups characteristics of both CaO and mesoporous H-ZSM-5 which appeared in the band at around 550 cm-1 and 480 cm-1. The isotherm of N2 adsorption-desorption of CaO/H-ZSM-5 indicated the type IV isotherm with the presence of hysteresis loop. For the catalytic activity, the biodiesel yield using catalyst of 10 % CaO/HZSM-5 (100 %), 30 % CaO/HZSM-5 (100 %), 50 % CaO/HZSM-5 (100 %) were 24.34, 27.37, and 29.73 %, respectively. It also related with the basic active site, when loading CaO increased, the basic active site also increased. Copyright © 2017 BCREC Group. All rights reservedReceived: 21st November 2016; Revised: 8th March 2017; Accepted: 9th March 2017; Available online: 27th October 2017; Published regularly: December 2017How to Cite: Purnamasari, A.P., Sari, M.E.F., Kusumaningtyas, D.T., Suprapto, S., Hamid, A., Prasetyoko, D. (2017). The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil. Bulletin of Chemical Reaction Engineering & Catalysis, 12(3): 329-336 (doi:10.9767/bcrec.12.3.802.329-336) |
| id |
IOS7652.article-802 |
| institution |
Universitas Diponegoro |
| institution_id |
69 |
| institution_type |
library:university library |
| library |
Departemen Politik dan Pemerintahan, Fakultas Ilmu Sosial dan Ilmu Politik |
| library_id |
2682 |
| collection |
Jurnal Ilmiah Ilmu Pemerintahan |
| repository_id |
7652 |
| subject_area |
Political dan Government Science/Ilmu Politik dan Ilmu Pemerintahan Policy Making/Keputusan Politik Election System/Pemilihan Umum, Pemilu Islam and Politics, Fundamentalism/Islam dan Ilmu Politik, Politik Islam, Fundamentalisme Islam |
| city |
Semarang |
| province |
JAWA TENGAH |
| repoId |
IOS7652 |
| first_indexed |
2020-03-20T11:17:52Z |
| last_indexed |
2020-03-20T11:17:52Z |
| recordtype |
dc |
| _version_ |
1686557433518882816 |
| score |
17.538404 |