Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone
| Main Authors: | Tai, Xi-Shi, Li, Peng-Fei, Liu, Li-Li |
|---|---|
| Other Authors: | National Natural Science Foundation of China (No. 21171132), the National Natural Science Foundation of Shandong (ZR2014BL003), the Project of Shandong Province Higher Educational Science and Technology Program (J14LC01), and Science Foundation of Weifang |
| Format: | Article info application/pdf Journal |
| Bahasa: | eng |
| Terbitan: |
Department of Chemical Engineering - Diponegoro University
, 2018
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| Subjects: | |
| Online Access: |
https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1961 https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1961/1857 |
Daftar Isi:
- A new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show that the Ca(II) complex molecules form 3D network structure by the interactions of π-π stacking and hydrogen bonds. The Ca(II) complex catalyst could efficiently catalyse oxidation of benzylic alcohol with good conversion of benzyl alcohol (78 %) and excellent selectivity of benzaldehyde (98 %).Copyright © 2018 BCREC Group. All rights reserved.Received: 13rd December 2017; Revised: 23rd May 2018; Accepted: 23rd May 2018How to Cite: Tai, X.S., Li, P.F., Liu, L.L. (2018). Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (3): 429-435 (doi:10.9767/bcrec.13.3.1961.429-435)Permalink/DOI: https://doi.org/10.9767/bcrec.13.3.1961.429-435