Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk
| Main Authors: | Chalim, Abdul, Wibowo, Agung Ari, Suryandari, Ade Sonya, Syarifuddin, Muhammad Muhajjir, Tohir, Moh. |
|---|---|
| Format: | Article info reaction kinetics application/pdf Journal |
| Bahasa: | eng |
| Terbitan: |
Politeknik Negeri Malang
, 2017
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| Subjects: | |
| Online Access: |
http://jtkl.polinema.ac.id/index.php/jtkl/article/view/23 http://jtkl.polinema.ac.id/index.php/jtkl/article/view/23/pdf |
| ctrlnum |
article-23 |
|---|---|
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<dc schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"><title lang="en-US">Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk</title><creator>Chalim, Abdul</creator><creator>Wibowo, Agung Ari</creator><creator>Suryandari, Ade Sonya</creator><creator>Syarifuddin, Muhammad Muhajjir</creator><creator>Tohir, Moh.</creator><subject lang="en-US">Chemical Engineering; Teknik Kimia</subject><subject lang="en-US">reaction kinetics; methanolysis; methyl ester sulfonate; batch reactor; surfactant</subject><subject lang="en-US">Chemical Reaction Engineering</subject><description lang="en-US">Surfaktan merupakan surface active agent yang banyak diaplikasikan dalam bidang industri kimia berkaitan dengan kemampuannya menstabilkan emulsi antara fasa minyak dan fasa air. Surfaktan berbasis minyak nabati merupakan pengembangan teknologi di bidang surfaktan yang selama ini didominasi oleh surfaktan berbahan baku minyak bumi. Metil ester sulfonat (MES) adalah surfaktan anionik yang dihasilkan melalui reaksi antara metil ester asam lemak dengan agen pensulfonasi atau yang lebih dikenal dengan reaksi sulfonasi. MES mengalami proses lanjutan yang disebut dengan reaksi metanolisis dan netralisasi. Penelitian ini mempelajari pengaruh rasio mol reaktan, waktu reaksi dan suhu reaksi terhadap yield MES pada reaksi metanolisis. Yield MES tertinggi yaitu 49,71% dicapai pada suhu reaksi 120°C, waktu reaksi 120 menit dan rasio mol MES terhadap metanol 1:3. Konstanta laju reaksi metanolisis ditentukan dengan mereaksikan reaktan di dalam reaktor batch berpengaduk pada kondisi operasi tersebut.Surfactant is a surface active agent which is widely applied in chemical industry related to its ability to stabilize the emulsion between the oil phase and the water phase. Surfactant-based on vegetable oil is a technology developed in the field of surfactant which has been dominated by surfactants made from petroleum. Methyl ester sulfonate (MES) is an anionic surfactant produced by the reaction between fatty acid methyl ester with a sulfonating agent or called as sulfonation reaction. MES undergoes an advanced process called methanolysis and neutralization reactions. This study investigated the effect of reactant molar ratio, reaction time and reaction temperature on MES yield on methanolysis reaction. The highest MES yield of 49.71% was achieved at a reaction temperature of 120°C, the reaction time of 120 minutes and the molar ratio between MES and methanol of 1:3. The rate constants of methanolysis reactions are determined by reacting the reactants in the stirred batch reactor under those operating conditions.</description><publisher lang="en-US">Politeknik Negeri Malang</publisher><contributor lang="en-US"/><date>2017-10-24</date><type>Journal:Article</type><type>Other:info:eu-repo/semantics/publishedVersion</type><type>Other:</type><type>Other:reaction kinetics</type><type>File:application/pdf</type><identifier>http://jtkl.polinema.ac.id/index.php/jtkl/article/view/23</identifier><identifier>10.33795/jtkl.v1i1.23</identifier><source lang="en-US">Jurnal Teknik Kimia dan Lingkungan; Vol 1, No 1 (2017): October 2017; 28-34</source><source>2579-9746</source><source>2579-8537</source><language>eng</language><relation>http://jtkl.polinema.ac.id/index.php/jtkl/article/view/23/pdf</relation><rights lang="en-US">Copyright (c) 2018 Abdul Chalim, Agung Ari Wibowo, Ade Sonya Suryandari, Muhammad Muhajjir Syarifuddin, Moh. Tohir</rights><rights lang="en-US">http://creativecommons.org/licenses/by-nc/4.0</rights><recordID>article-23</recordID></dc>
|
| language |
eng |
| format |
Journal:Article Journal Other:info:eu-repo/semantics/publishedVersion Other Other: Other:reaction kinetics File:application/pdf File Journal:Journal |
| author |
Chalim, Abdul Wibowo, Agung Ari Suryandari, Ade Sonya Syarifuddin, Muhammad Muhajjir Tohir, Moh. |
| title |
Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk |
| publisher |
Politeknik Negeri Malang |
| publishDate |
2017 |
| topic |
Chemical Engineering Teknik Kimia reaction kinetics methanolysis methyl ester sulfonate batch reactor surfactant Chemical Reaction Engineering |
| url |
http://jtkl.polinema.ac.id/index.php/jtkl/article/view/23 http://jtkl.polinema.ac.id/index.php/jtkl/article/view/23/pdf |
| contents |
Surfaktan merupakan surface active agent yang banyak diaplikasikan dalam bidang industri kimia berkaitan dengan kemampuannya menstabilkan emulsi antara fasa minyak dan fasa air. Surfaktan berbasis minyak nabati merupakan pengembangan teknologi di bidang surfaktan yang selama ini didominasi oleh surfaktan berbahan baku minyak bumi. Metil ester sulfonat (MES) adalah surfaktan anionik yang dihasilkan melalui reaksi antara metil ester asam lemak dengan agen pensulfonasi atau yang lebih dikenal dengan reaksi sulfonasi. MES mengalami proses lanjutan yang disebut dengan reaksi metanolisis dan netralisasi. Penelitian ini mempelajari pengaruh rasio mol reaktan, waktu reaksi dan suhu reaksi terhadap yield MES pada reaksi metanolisis. Yield MES tertinggi yaitu 49,71% dicapai pada suhu reaksi 120°C, waktu reaksi 120 menit dan rasio mol MES terhadap metanol 1:3. Konstanta laju reaksi metanolisis ditentukan dengan mereaksikan reaktan di dalam reaktor batch berpengaduk pada kondisi operasi tersebut.Surfactant is a surface active agent which is widely applied in chemical industry related to its ability to stabilize the emulsion between the oil phase and the water phase. Surfactant-based on vegetable oil is a technology developed in the field of surfactant which has been dominated by surfactants made from petroleum. Methyl ester sulfonate (MES) is an anionic surfactant produced by the reaction between fatty acid methyl ester with a sulfonating agent or called as sulfonation reaction. MES undergoes an advanced process called methanolysis and neutralization reactions. This study investigated the effect of reactant molar ratio, reaction time and reaction temperature on MES yield on methanolysis reaction. The highest MES yield of 49.71% was achieved at a reaction temperature of 120°C, the reaction time of 120 minutes and the molar ratio between MES and methanol of 1:3. The rate constants of methanolysis reactions are determined by reacting the reactants in the stirred batch reactor under those operating conditions. |
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Politeknik Negeri Malang (Polinema) |
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Jurusan Teknik Kimia (TK) Polinema |
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| subject_area |
General Topics of Chemical Engineering/Topik-topik Umum Teknologi Kimia Thermodynamics/Termodinamika Energy/Energi Environmental Chemistry/Kimia Lingkungan |
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KOTA MALANG |
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JAWA TIMUR |
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2017-12-18T00:30:14Z |
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