EFFECT OF CATALYST AND FEED RATIO TO CPO CONVERSION IN BIODIESEL PROCESS
Main Authors: | Sari, Tuti Indah, Said, M., Hambali, Mulkan |
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Format: | Article PeerReviewed application/pdf |
Terbitan: |
Assosiasi Pendidikan Tinggi Teknik Kimia Indonesia
, 2006
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Subjects: | |
Online Access: |
http://eprints.unsri.ac.id/2316/1/KKR_25.pdf http://eprints.unsri.ac.id/2316/ |
ctrlnum |
2316 |
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fullrecord |
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<dc schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"><title>EFFECT OF CATALYST AND FEED RATIO
TO CPO CONVERSION IN BIODIESEL PROCESS</title><creator>Sari, Tuti Indah</creator><creator>Said, M.</creator><creator>Hambali, Mulkan</creator><subject>QD Chemistry</subject><subject>TP Chemical technology</subject><description>Process of alcoholises between Crude Palm Oil (CPO) and methanol with HCl as catalyst was
conducted in a batch reactor equipped with heater, thermometer, and sampling apparatus to produce
methyl ester for bio diesel. Bio diesel produced could be used as alternative fuel regarding with energy
diversification using renewable fuel.
Process variables included ratio of CPO and methanol, that is 1 : 3, 1 : 5, and 1 : 7, reaction
temperature of 70, 90 , and 110 0C, and reaction time of 20, 40, 60 minutes. HCL 37 % was used as
catalyst with the amount of 2 % from volume of CPO and agitation of 100 rpm. The amount of glycerol
formed, free fatty acid, and total fatty acid were analyzed to determine conversion of the reaction.
The amount of conversion was influenced by ratio of CPO and methanol, temperature, and
reaction time. The conversion increased with the increase of ratio of CPO and methanol, temperature,
and reaction time. The highest conversion of 70.4 % was found at the ratio of CPO and methanol,
temperature, and reaction time of 1:7, 110 0C, and 60 minutes, respectively. Reaction kinetic constant
increased as reaction temperature elevated. The highest reaction constant of 1,080x10-2 minutes-1 was
found at 110 0C.
Keywords: CPO, bio diesel, alcoholises, kinetic reaction.</description><publisher>Assosiasi Pendidikan Tinggi Teknik Kimia Indonesia</publisher><date>2006-07-19</date><type>Journal:Article</type><type>PeerReview:PeerReviewed</type><type>File:application/pdf</type><identifier>http://eprints.unsri.ac.id/2316/1/KKR_25.pdf</identifier><identifier>Sari, Tuti Indah and Said, M. and Hambali, Mulkan (2006) EFFECT OF CATALYST AND FEED RATIO TO CPO CONVERSION IN BIODIESEL PROCESS. Seminar Nasional Teknik Kimia Indonesia 2006. KKR 25-1. ISSN 979-97893-0-3</identifier><relation>http://eprints.unsri.ac.id/2316/</relation><recordID>2316</recordID></dc>
|
format |
Journal:Article Journal PeerReview:PeerReviewed PeerReview File:application/pdf File |
author |
Sari, Tuti Indah Said, M. Hambali, Mulkan |
title |
EFFECT OF CATALYST AND FEED RATIO
TO CPO CONVERSION IN BIODIESEL PROCESS |
publisher |
Assosiasi Pendidikan Tinggi Teknik Kimia Indonesia |
publishDate |
2006 |
isbn |
9789799789303 |
topic |
QD Chemistry TP Chemical technology |
url |
http://eprints.unsri.ac.id/2316/1/KKR_25.pdf http://eprints.unsri.ac.id/2316/ |
contents |
Process of alcoholises between Crude Palm Oil (CPO) and methanol with HCl as catalyst was
conducted in a batch reactor equipped with heater, thermometer, and sampling apparatus to produce
methyl ester for bio diesel. Bio diesel produced could be used as alternative fuel regarding with energy
diversification using renewable fuel.
Process variables included ratio of CPO and methanol, that is 1 : 3, 1 : 5, and 1 : 7, reaction
temperature of 70, 90 , and 110 0C, and reaction time of 20, 40, 60 minutes. HCL 37 % was used as
catalyst with the amount of 2 % from volume of CPO and agitation of 100 rpm. The amount of glycerol
formed, free fatty acid, and total fatty acid were analyzed to determine conversion of the reaction.
The amount of conversion was influenced by ratio of CPO and methanol, temperature, and
reaction time. The conversion increased with the increase of ratio of CPO and methanol, temperature,
and reaction time. The highest conversion of 70.4 % was found at the ratio of CPO and methanol,
temperature, and reaction time of 1:7, 110 0C, and 60 minutes, respectively. Reaction kinetic constant
increased as reaction temperature elevated. The highest reaction constant of 1,080x10-2 minutes-1 was
found at 110 0C.
Keywords: CPO, bio diesel, alcoholises, kinetic reaction. |
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