EFFECT OF CATALYST AND FEED RATIO TO CPO CONVERSION IN BIODIESEL PROCESS

Main Authors: Sari, Tuti Indah, Said, M., Hambali, Mulkan
Format: Article PeerReviewed application/pdf
Terbitan: Assosiasi Pendidikan Tinggi Teknik Kimia Indonesia , 2006
Subjects:
Online Access: http://eprints.unsri.ac.id/2316/1/KKR_25.pdf
http://eprints.unsri.ac.id/2316/
ctrlnum 2316
fullrecord <?xml version="1.0"?> <dc schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"><title>EFFECT OF CATALYST AND FEED RATIO&#xD; TO CPO CONVERSION IN BIODIESEL PROCESS</title><creator>Sari, Tuti Indah</creator><creator>Said, M.</creator><creator>Hambali, Mulkan</creator><subject>QD Chemistry</subject><subject>TP Chemical technology</subject><description>Process of alcoholises between Crude Palm Oil (CPO) and methanol with HCl as catalyst was&#xD; conducted in a batch reactor equipped with heater, thermometer, and sampling apparatus to produce&#xD; methyl ester for bio diesel. Bio diesel produced could be used as alternative fuel regarding with energy&#xD; diversification using renewable fuel.&#xD; Process variables included ratio of CPO and methanol, that is 1 : 3, 1 : 5, and 1 : 7, reaction&#xD; temperature of 70, 90 , and 110 0C, and reaction time of 20, 40, 60 minutes. HCL 37 % was used as&#xD; catalyst with the amount of 2 % from volume of CPO and agitation of 100 rpm. The amount of glycerol&#xD; formed, free fatty acid, and total fatty acid were analyzed to determine conversion of the reaction.&#xD; The amount of conversion was influenced by ratio of CPO and methanol, temperature, and&#xD; reaction time. The conversion increased with the increase of ratio of CPO and methanol, temperature,&#xD; and reaction time. The highest conversion of 70.4 % was found at the ratio of CPO and methanol,&#xD; temperature, and reaction time of 1:7, 110 0C, and 60 minutes, respectively. Reaction kinetic constant&#xD; increased as reaction temperature elevated. The highest reaction constant of 1,080x10-2 minutes-1 was&#xD; found at 110 0C.&#xD; Keywords: CPO, bio diesel, alcoholises, kinetic reaction.</description><publisher>Assosiasi Pendidikan Tinggi Teknik Kimia Indonesia</publisher><date>2006-07-19</date><type>Journal:Article</type><type>PeerReview:PeerReviewed</type><type>File:application/pdf</type><identifier>http://eprints.unsri.ac.id/2316/1/KKR_25.pdf</identifier><identifier>Sari, Tuti Indah and Said, M. and Hambali, Mulkan (2006) EFFECT OF CATALYST AND FEED RATIO TO CPO CONVERSION IN BIODIESEL PROCESS. Seminar Nasional Teknik Kimia Indonesia 2006. KKR 25-1. ISSN 979-97893-0-3</identifier><relation>http://eprints.unsri.ac.id/2316/</relation><recordID>2316</recordID></dc>
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author Sari, Tuti Indah
Said, M.
Hambali, Mulkan
title EFFECT OF CATALYST AND FEED RATIO TO CPO CONVERSION IN BIODIESEL PROCESS
publisher Assosiasi Pendidikan Tinggi Teknik Kimia Indonesia
publishDate 2006
isbn 9789799789303
topic QD Chemistry
TP Chemical technology
url http://eprints.unsri.ac.id/2316/1/KKR_25.pdf
http://eprints.unsri.ac.id/2316/
contents Process of alcoholises between Crude Palm Oil (CPO) and methanol with HCl as catalyst was conducted in a batch reactor equipped with heater, thermometer, and sampling apparatus to produce methyl ester for bio diesel. Bio diesel produced could be used as alternative fuel regarding with energy diversification using renewable fuel. Process variables included ratio of CPO and methanol, that is 1 : 3, 1 : 5, and 1 : 7, reaction temperature of 70, 90 , and 110 0C, and reaction time of 20, 40, 60 minutes. HCL 37 % was used as catalyst with the amount of 2 % from volume of CPO and agitation of 100 rpm. The amount of glycerol formed, free fatty acid, and total fatty acid were analyzed to determine conversion of the reaction. The amount of conversion was influenced by ratio of CPO and methanol, temperature, and reaction time. The conversion increased with the increase of ratio of CPO and methanol, temperature, and reaction time. The highest conversion of 70.4 % was found at the ratio of CPO and methanol, temperature, and reaction time of 1:7, 110 0C, and 60 minutes, respectively. Reaction kinetic constant increased as reaction temperature elevated. The highest reaction constant of 1,080x10-2 minutes-1 was found at 110 0C. Keywords: CPO, bio diesel, alcoholises, kinetic reaction.
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