Daftar Isi: Influence of TiO2/TS-1 Calcination on Hydroxylation of Phenol

Main Authors:	Ediati, Ratna; Department of Chemistry, Faculty of Mathematic and Natural Sciences, Institut Teknologi Sepuluh Nopember, Ulfa, Maria; Department of Chemistry, Faculty of Mathematic and Natural Sciences, Institut Teknologi Sepuluh Nopember, Fansuri, Hamzah; Department of Chemistry, Faculty of Mathematic and Natural Sciences, Institut Teknologi Sepuluh Nopember, Ramli, Zainab; Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia, Nur, Hadi; Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia, Prasetyoko, Didik; Department of Chemistry, Faculty of Mathematic and Natural Sciences, Institut Teknologi Sepuluh Nopember
Format:	Article info application/pdf eJournal
Bahasa:	eng
Terbitan:	ITB Journal Publisher, LPPM ITB , 2014
Subjects:	anatase calcinations phenol hydroxylation rutile TiO2/TS-1
Online Access:	http://journals.itb.ac.id/index.php/jmfs/article/view/818 http://journals.itb.ac.id/index.php/jmfs/article/view/818/497

Daftar Isi:

Titanium oxide (TiO2) was impregnated on the surface of titanosilicate-1 (TiO2/TS-1) and used as catalyst for hydroxylation of phenol with hydrogen peroxide. Calcination was conducted at various temperatures (400, 500, 600 and 700°C)in order to observe the effect on the structure and physicochemical properties towards catalytic activity for producing hydroquinone. The structure and physicochemical properties of the TiO2/TS-1 catalyst were characterized by several techniques, such as X-ray diffraction (XRD), infrared spectroscopy, nitrogen adsorption, pyridine adsorption and hydrophilic measurement. The results show that by increasing the calcination temperature,the surface acidity of the catalyst was also increased.TheTiO2/TS-1 catalyst calcined at 500°Cproved to be optimal for hydroquinone production, in which the anatase-rutile phase may be present dispersed on the MFI framework.