N2-sorption and catalytic results of doped Cu-catalysts for glycerol hydrogenolysis
| Main Authors: | Alexandra Bouriakova, Pedro S. F. Mendes, Benjamin Katryniok, Jeriffa De Clercq, Joris W. Thybaut |
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| Format: | info dataset eJournal |
| Terbitan: |
, 2020
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/3739138 |
Daftar Isi:
- This repository includes experimental data associated with the following publication: A. Bouriakova et al., "Dopant induced stabilization of alumina supported copper – impact on the catalytic performance in the hydrogenolysis of glycerol to 1,2-propanediol", submitted to Catalysis Communications in April 2020 In this work, five catalysts supported on γ-Al2O3 were studied, i.e. one bare Cu and four doped-Cu catalysts. The catalysts were prepared via sequential impregnation. The nominal dopant loading was 1wt%, for the Cu a nominal value of 10wt% was selected: - 10wt% Cu/-Al2O3, indicated as Cu - 1wt%Ba-10wt% Cu/-Al2O3, indicated as Ba-Cu - 1wt%Ce-10wt% Cu/-Al2O3, indicated as Ce-Cu - 1wt%Cs-10wt% Cu/-Al2O3, indicated as Cs-Cu - 1wt%La-10wt% Cu/-Al2O3, indicated as La-Cu The catalysts were investigated for 68 h for continuous flow pure glycerol hydrogenolysis in a trickle bed regime at 473 K, 7.5 MPa, 135 kgcat s mol-1glycerol and 7 molH2 mol-1glycerol, and compared for glycerol conversion, 1,2-propanediol selectivity and stability. The data file contains the glycerol conversion and selectivities over time for the studied catalysts, in combination with N2-sorption data of those catalysts. In addition, an overview of literature data on glycerol hydrogenolysis is given (Fig 1 in the manuscript).