lnfluence of Ortho Substituents on Intramolecular Hydrogen Bonding

Main Authors: V. Baliah, (Miss) M. Uma
Format: Article
Bahasa: eng
Terbitan: , 1962
Subjects:
Online Access: https://zenodo.org/record/6529997
Daftar Isi:
  • Ultraviolet absorption spectra of some substituted o- and p-nitrophenols in ethanol and in cyclohexane are recorded and analysed with a view to finding the influence of ortho substituents on intramolecular hydrogen bonding. A methyl group, ortho to —OH, is peen to have no signficant effect on the hydrogen bond, but a methyl group, ortho to — NO2, renders the hydrogen bond very weak, though hydrogen-bond formation is not prevented.