A Study of the Chloro Complexes of Cobalt (II) using Liquid Anion-exchange and Spectrophotometry
| Main Authors: | K. S. Venkateswarin, Manohar Lai |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1964
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6510638 |
Daftar Isi:
- using-n-nonylamine in benzene sq the extrantant for cobalt(II) from HCI solutions, the increase in the percentage extraction has been found up to 8M-HCI; it decreases with further increase in HCI molarity. At 3.5. 6.8.5, and 11M- HCI, the distribution coefficient has been determined, taking different per. centages of the amine in the diluent. The experimental data have been analysed by plotting log D against a ±HCl or log % amine. From this it is concluded that the ion pair in the solvent phase may be [RNFH]2+ (CoCI4)2—. The result has been confirmed by spectroptotometric method.