Behaviour of Diazotised Sulphanilamides with Reactive Unsaturated Compounds. Substituted Sulphamidocinnamic Acids

Main Authors: Anil Prakash, I. R. Gambhir
Format: Article Journal
Bahasa: eng
Terbitan: , 1966
Subjects:
Online Access: https://zenodo.org/record/6488416
Daftar Isi:
  • Diazonium chloriders of sulphanilamidopyrimidinas reset at pH 1.0 in presence of cupric chloride wish acrylonitrile, acrylic eater, crotonic avid, and protonic ester to furnish \(\alpha\)-ohloro-p-pyrimidylsulphamido­hydrocinnamic acid derivatives which on heating with EtOH-NaOH are converted into p-pyrimidyleulpha­mideeinnamio acids. Haleic said, however, yields \(\alpha\)-chloro-\(\beta\)-carboxy-p-pyrimidylsulphatmide-hydro­oinnamis acid at pH 1.0 and p-pyrimidylonlpharaidoeinnamin acid at pH 3.0.