Calculation of the Size, b* and Dipolemoment, G* of the Active Group in the Activated Complex in Ion-Dipole type of Reactions in Solution
| Main Authors: | R. C. JHA, LALLAN SINGH, S. N. DAS |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1974
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6416550 |
Daftar Isi:
- Department of Chemistry, Science College, Patna. Manuscript received 19 October 1973; accepted 30 May 1914 Laidler and Landskroener 9 have derived an equation for calculating b*, the size of the active group of an activated complex in ion-dipolar molecule type of reactions in solution, in which the transition state is highly polarized. They have calculated G* theoretically by assuming a specific model of the transition state and the distribution of charges within the molecule. An attempt has been made to calculate b* and G* directly without any assumption about the model of the transition state, on the basis of the variation of rate coefficient in a binary solvent mixture.