Kinetics of the Oxidation of Acetophenone by Chloramine-T in Acid Medium
| Main Authors: | K.J. SINGH, (Miss) NALINI RAINA |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1977
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6396938 |
Daftar Isi:
- Department of Chemistry, Government Science College, Gwalior (M.P.) Manuscript received 4 June 1976; accepted 28 August 1976 The kinetic measurements of the oxidation of acetophenone have been made in 25% aqueous acetic acid. The oxidation reaction is first order each in ketone and chloramine- T. The first order rate constant k1 is proportional to [H+]. Effect of neutral salt viz. NaClO4 and KCl shows the reaction to exhibit a positive salt effect. Arrhenius parameters have been computed. The mechanism has been proposed on the basis of experimental results.