Thermodynamic Metal-Ligand Stability Constants of Pd(II), Pt(II), Rh(III) and Fe(III) Complexes of Biuret
| Main Authors: | P. C. SRIVASTAVA, B. K BANERJEE |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1979
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6388482 |
Daftar Isi:
- Physical Research Wing, Fertilizer (P & D) India Ltd., Sindri-823 122, Dhanbad (Bihar), India Manuscript received 6 November 1978, accepted 6 June 1979 Potentiometric studies on complexes of biuret with Pd(II), Pt(II), Rh(III) and Fe(III) at different ionic strengths (μ=0.2M, 0.15M, 0.10M and 0.05M) have been carried out at room temperature 25(±0.02)°. The Calvin-Bjerrum \(p\)H titration technique as used by Irving and Rossotti has been applied to determine the dissociation Constants of biuret and successive stability constants of metal complexes. The covalent nature and π-bonding of metal-ligand have been discussed in detail.