Exciton coupling chirality in helicene-porphyrin conjugates
| Main Authors: | Dhbaibi Kais, Matozzo Paola, Abella Laura, Jean Marion, Vanthuyne Nicolas, Autschbach Jochen, Favereau Ludovic, Crassous Jeanne |
|---|---|
| Format: | Article Journal |
| Terbitan: |
, 2021
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| Online Access: |
https://zenodo.org/record/6375060 |
Daftar Isi:
- Enantiopure helicene-porphyrin conjugates were prepared. They show strong changes in their circular dichroic response as compared to classical helicene derivatives, with highly intense bisignate Exciton Coupling (EC) signal and De values up to 680 M-1 cm-1 for the Soret band. They also display circularly polarized fluorescence in the (far-)red region, with dissymmetry factors up to 7 x 10-4.