Studies on Metal Ammine Complexes-Part II. Polarographic Behaviour of Some Schiff Base Pentaammine Chromium(lll) Complexes
| Main Authors: | W. U. MALIK, R. BEMBI, P. P. BHARGAVA, SUSHILA, O. P. TANDON |
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| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1980
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6364088 |
Daftar Isi:
- Department of Chemistry, University of Roorkee, Roorkeo-247 672 Manuscript received 9 March 1979, revised 24 September 1979, accepted 4 March 1980 The polarographic behaviour of several newly synthesised chromium(III) complexes with Schiff bases has been described. The reduction waves in 0.1 M LiCI corresponded to one electron reduction These are diffusion controlled and irreversible in nature. The values of k° f,h lie between 10-9 to 10-11 cm-1s-1. The irreversitle behaviour may be interpreted in terms of 'Loosening' of the chromium(IIl) complex during reduction from Cr(III) to Cr(ll). The complexes have been characterised by chemical analysis, conductance measurements and infrared spectra.