Adducts of Copper(ll) Carboxylates of Unsaturated Acids with Heterocyclic Nitrogen Bases
| Main Authors: | N. KUMAR, A. K. SURl |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1981
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6364078 |
Daftar Isi:
- Department of Chemistry, University of Jammu, Jammu-180 001 Manuscript received 23 February 1981, accepted 9 June 1981 Copper(II) carboxylates of unsaturated acids of formula Cu(O2CCH=CHR)2 [where R=CH2 and C6H5] have been prepared and characterized. They yield two series of adducts of composition Cu(O2CCH=CHR)2. L and Cu(O2CCH=CHR)2 . 2L' where L=2-methylpyridine (2-MePy), quinoline (Q) and L' =pyridine (Py), 3- methylpyridine (3-MePy), isoquinoline (IQ) and morpholine (Morph). Molar conductance studies show them to be non-electrolytic. Molecular weight studies show that 1 : 1 adducts are dimeric. These have been shown by magnetic and spectral studies to possess a carboxylate bridged structure similar to that of copper( II) acetate monohydrate, whilst 1 : 2 adducts are hexa-coordinated polymeric species containing antianti bridging carboxylate groups.