Transition Metal Complexes of Cinnamoylhydrazine

Main Authors: M. M. MOSTAFA, S.M. HASSAN, A. A. EL-ASMY
Format: Article Journal
Bahasa: eng
Terbitan: , 1980
Subjects:
Online Access: https://zenodo.org/record/6364034
Daftar Isi:
  • Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt Manuscript received 5 March 1979, accepted 29 December 1979 Cinnamoylhydrazine (CH) form complexes with Co(II), N(II), Fe(III), Cr(III), Zn(II), Cd(H), and Hg(II). Their structures have been proposed on the basis of analytical, conductance and infrared data. Hg(II), Cd(II), Mn(II) and Zn(II) complexes coordinate via carbonyl oxygen and NH2 groups, while Co(Il), Ni(II), Fe(III) and Cr(III) complexes coordinate through the imidol structure. Spectral data confirm the tetrahedral structure for cobalt chloride and bromide, a square planar structure for Ni and an octahedral structure for Cr.