Synthesis and Characterization of Pseudohalides of Bis-Methylcyclopentadienyl Titanium(IV)
| Main Authors: | V. K. JAIN, N. K. BHATIA, K. C. SHARMA, B. S. GARG |
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| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1980
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6361253 |
Daftar Isi:
- Department of Chemistry, University of Delhi, Delhi-110 007 (India) Manuscript received 24 September 1979, accepted 30 November 1979 The pseudohalide complexes of the (ɳ-CH2C5H4)2TiX2 type (where X=N2, NCS, NCO and NCSe) have been prepared in aqueous medium (pH~2) as well as in non-aqueous medium. These complexes have been characterized by elemental analyses, IR and NMR spectroscopy. These complexes are monomeric in benzene solution and non-electrolytes in nitrobenzene solution. On the basis of infrared spectroscopy, it has been shown that NCS, NCO and NCSe are N-bonded to the titanium atom. Thus these are true isothiocyanato, isocyanato and isoselenocyanato derivatives. The proton chemical shifts of these complexes have also been reported.