Studies on the Behaviour of Cobalt and Calcium Soaps. Part IV Solubilization of Water and Its Effect on Conductance Behaviour in Alcohols
| Main Authors: | R. P. VARMA, P. K. JAIN |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1981
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6358762 |
Daftar Isi:
- Department of Chemistry, D. A. V. College, Muzaffarnagar-251 001 Manuscript received 23 October 1979, revised 12 August 1980, accepted 10 March 1981 Solubilization of water in 1-butanol and 3-methyl-1-butanol has been studied in presence of cobalt and calcium soaps at 35-50°. Maximum additive concentration increases with increasing temperature and also with soap concentration below CMC. Addition of water increases the CMC of these soaps in alcohols. The conductance behaviour or soap solutions in presence or varying amounts of water is expressed by an equation log \(\lambda\)= A+B log C. Constants, -A and -B decrease with increasing amount of water. These values in 3-methyl-1-butanol are higher than the values in 1-butanol. Dissociation constant, K and molecular conductivity at infinite dilution, \(\lambda\)\({x}\) have been calculated and are found to increase with increasing amount of water.