Kinetics of Nickel(II) Ion and Cobalt(II) Ion Catalysed Hydroxamic Acid Formation from Formic Acid

Main Authors: M. H. JAGDALE, M. M. SALUNKHE, S. S. SWAMI
Format: Article Journal
Bahasa: eng
Terbitan: , 1982
Subjects:
Online Access: https://zenodo.org/record/6358400
Daftar Isi:
  • Department of Chemistry, Shivaji University, Kolhapur-416 004 Manuscript received 17 March 1981, revised 18 September 1981, accepted 7 January1982 The Kinetics or Ni(II) ion catalysed formation of hydroxamic acid from formic acid and hydroxylamine revealed to be first order each with respect to formic acid, hydroxylamine and Ni(ll) Jon concentration. Cobalt(II) ion Is comparable with Ni(ll) ion in its catalytic efficiency, but Its catalytic effect Is weaker than that or the Ni(II) ion. The activation parameters have been evaluated and a probable mechanism has been suggested.