Preparative and Structural Studies on Bimetallic Tetradithiocarbamates of Some Bivalent 3d-Metal Ions
| Main Authors: | R. C. AGGARWAL, B. SINGH, M. K. SINGH |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1982
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6353203 |
Daftar Isi:
- Department of Chemistry. Banaras Hindu University, Varanasi-221 005 Some novel bimetallic tetradithiocarbamates, MCd(Dtc)4 , M=VO(IV), Mn(II), Fe(ll), Co(II), Ni(II), Cu(II) or Zn(II); Dtc=piperidine dithio. carbamate (pDtc) or diethyldithiocarbamate (Et2Dtc), have been prepared for the first time and characterised on the basis of analytical data, molar conductance, magnetic susceptibilty, electronic, esr and Infrared spectral measurements. Tetrahedral coordination around Zn(II) and Cd(II), square Pyramidal coordination around VO(IV) and square planar coordination around Mn(II), Fe(II), Co(II), NI(II) and Cu(II) have been proposed In bimetallic tetradithiocarbamates