Kinetics of Oxidation of Acetaldehyde by Chloramine-T in Acid Medium
| Main Authors: | D. S. MAHADEVAPPA, M. B. JADHAV, H. M. K. NAIDU |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1981
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6352758 |
Daftar Isi:
- Department of Post-Graduate Studies and Research in Chemistry, University of Mysore, Manasagan gotri, Mysore-570 006 Manuscript received 19 June 1980, accepted 10 March 1981 The kinetics of oxidation of acetaldehyde by Chloramine-T in HCl, HCl, HCLO4 and H2SO4 media shows a first order dependence each on oxidant, substrate and [H+] ion concentrations, but the rate law reduces to Rate=k [CAT] at higher aldehyde and hydrogen ion concentrations. A mechanism in terms of a slow interaction between N-chlorotoluenesulphonamide and the aldehyde molecule is proposed.