Polarographic Reduction of Some 5,5-Dimethylcyclohexarle- 2-Benzothiazolylhydrazono-1,3-Diones and its 2-Methyl, 4-Methyl, 4-Methoxy, 4-Ethoxy Derivatives
| Main Authors: | WAHID U. MALIK, (Miss) S. AGARWAL, RAJEEV JAIN |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1982
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6351589 |
Daftar Isi:
- Department of Chemistry, University of Roorkee, Roorkee-247 672 Manuscript received 2 April 1982, accepted 21 July 1982 Polarographic studies of some 5,5-dimethylcyclohexane-2-benzothiazolylhydrazono-1,3-diones were carried out in B. R. buffer in the pH range 2.0-12.0. All the compounds gave a single, well defined, irreversible, diffusion controlled reduction wave. whose E1/2. was pH dependent but id remained constant throughout the entire pH range. The E1/2, shifted towards negative potential with increase in pH, thereby showing that protonation precedes reduction. The effect of the double layer structure on the E1/2, is also studied.