Stabilisation of Molybdenyl Cations with 4,4/-Dimethyl 2,2-Bipyridyl in Different Salt and Non-electrolytic Complexes
| Main Authors: | H. K. SAHA, S. S. MANDAL, P. C. GHORAl |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1982
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6351317 |
Daftar Isi:
- Pure Chemistry Department, University College of Science, Calcutta-700 009 Manuscript received 16 October 1981, rowed 14 April 1982, accepted 21 July 1982 The aqueous chemistry of molybdenyl cation MoO3+ has been studied. The heterocyclic base 4,4'-dimethyl 2,2'-bipyridyl has been shown to function as diacidic base in strong hydrochloric acid medium to yield the salt Me2bipyH2[MoOCl5]. The non-electrolytic complexes (Mo2O4CI2(Me2bipy)2] and [MoOCl3 Me2bipy] have been isolated from the parent salt by hydrolytic and debydrohalogenation reactions in solution and in solid state.