Thorium(IV) Fluorosulphate
| Main Authors: | R. C. PAUL, SUKHJINDER SINGH, K. D. VERMA |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1981
|
| Subjects: | |
| Online Access: |
https://zenodo.org/record/6349924 |
Daftar Isi:
- Department of Chemistry, Panjab University, Chandigarh-160 014 Manuscript received 12 May 1980, accepted 29 October 1980 Th(SO3F)4, [A], has been prepared by the action of HSO3F on Th(O2CCH3)4• The i r. spectrum indicates bidentate nature of SO3F groups. It forms adducts with pyridine (Py), quinoline (Q), dimethylsulphoxide (DMSO), triphenylpbosphineoxide (TPPO) and bipyridyl (Bipy) of the compositions, A. 2Py, A. 2Q, A. 2DMSO, A. 2TPPO and A. Bipy respectively. SO3F groups in these complexes are also bidentate as shown by their i.r. spectra. Th(SO3F)4 decomposes thermally in a single step with evolution of SO2F2 and formation of Th(SO4)2 •