Kinetic Study of Ag(l) Catalysed Oxidation of Glycine by Ce(IV) in Perchloric Acid Medium
| Main Authors: | BHARAT SINGH, CHANDRA PAL SINGH GAUR, RAS BIHAR! SINGH, B. B. L. SAXBNA |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1982
|
| Subjects: | |
| Online Access: |
https://zenodo.org/record/6348715 |
Daftar Isi:
- Department of Chemistry, University of Allahabad, Allahabad-211 002 Manuscript received 25 January 1980, revised 9 July 1981, accepted 30 October 1981 The kinetics of Ag(l) catalysed oxidation of glycine by ceric perchlorate in perchloric acid solution are reported. The reaction follows first-order kinetics with respect to each Ce(IV), glycine and perchloric acid. The reaction rate is found to be accelerated by Ag(I). Formic acid and ammonia are found to be reaction products. A suitable mechanism involving formation of a transient complex [glycine-Ce(IV)] has been proposed.