Determination of Stability Constants of the Complexes of 4-Hydroxy-3-aldehydobiphenyl with Cu2+, Ni2+, Co2+, Zn2+ and Mg2+
| Main Authors: | M. S. MAYADEO, D. N. PATEL |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1983
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6348470 |
Daftar Isi:
- Department of Chemistry, Ramnaraiu Ruia College, Matunga, Bombay-400 019 Manuscript received 17 February 1982, accepted 10 December 1982 Complexation equilibria of metal complexes of CO2+, Ni2+, Co2+, Zn2+ and Mg2+ with 4-hydroxy-3-aldehydobiphenyl have been studied potentiometrically. The proton dissociation constant of the reagent and the dissociation constants of its metal complexes have been determined by Bjerrum-Calvin \(p\)H titration technique as adopted by Irving and Rossotti at 30 \(\pm\) 0.1° and at ionic strength of μ= 0.1 M in 75 : 25 v/v dioxane-water medium. The order of the stability constants of the chelates was found to be Cu>Zn>Co>Ni>Mg.