Complex Formation of Vanadium(V) with N-AHA Extractive Photometric Methods of Determination of Trace Vanadium in Geological Materials and Alloy and Extraction Constants

Main Authors: S. P. BAG, A. B. CHATTERJEE, A. K. CHAKRABARTI, P. R. CHAKRABORTY
Format: Article Journal
Bahasa: eng
Terbitan: , 1983
Subjects:
Online Access: https://zenodo.org/record/6348391
Daftar Isi:
  • Department of Chemistry, Jadavpur University, Calcutta-700 032 Manuscript received 14 June 1982, accepted 28 December 1982 Reactions of vanadium(V) with N-anthranilohydroxamic acid under varying condi­tions of \(p\)H and acidity and extraction behaviour of the complexes in methyl isobutyl ketone is reported. New sensitive and selective photometric methods for trace deter­mination of vanadium(V) in absence or presence of thiocyanate and its applications in the analyses of high speed steel, ilmenite and bauxite are described. The stepwise stability and extraction constants have been determined by absorptiometric methods and reported.