Studies on the Preparation and Characterization of Monochlorodithiocarbamato Complexes of Di-n-Butyl- and Di-n-Hexyltin(IV)
| Main Authors: | C. P. SHARMA, N. KUMAR, S. CHANDRA, B. S. GARG |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1983
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6348271 |
Daftar Isi:
- National Physical Laboratory, New Delhi-110 012 Department of Chemistry, University of Delhi, Delhi-110 007 Manuscript received 19 February 1982, revised 23 August 1982, accepted 28 January 1983 Dialkyltin(IV) rnonochlorodithiocarbamato complexes of the type R2Sn(IV)-[R'R"dtc]CI or R2Sn(IV)[morph.dtc]CI (R=n-Bu, n-Hex, R'=R"=Me, Et, i-Pr; R'= Me and R" =Ph) have been prepared by the reaction of di-n-butyl- or di-n-hexyltin(IV) dichloride with the sodium salt of respective dithiocarbamic acid in 1 : 1 molar ratio in dry acetone. The ir, 1H mnr and Mossbauer studies indicate an anisobidentate character for the dtc (dithiocarbamate) ligand in these complexes.