Analysis of the Ignition Products of Unsymmetrical Dimethyl Hydrazine with Nitric Acid and the Probable Reaction Mechanism
| Main Authors: | S. P. SINGH, R. K. PRASAD |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1983
|
| Subjects: | |
| Online Access: |
https://zenodo.org/record/6345891 |
Daftar Isi:
- Department of Chemistry, R. D. S. College, Muzaffarpur Poet-Graduate Department of Chemistry, Bihar University, Muzaffarpur Manuscript received 4 January 1982, reamed 22 September 1982, accepted 10 December 1982 The reaction products of unsymmetrical dimethyl hydrazine (UDMH) with nitric acid, under ignition and near ignition conditions have been examined through methods of instrumental analysis. Spectroscopic methods which include uv, ir, nmr and mass spectra have been used for the liquid products and gas chromatography for the gaseous and the liquid products. A mechanism for the reaction is proposed on the basis of the known chemistry of UDMH and HNO3 as well as reactions and intermediates that are known and on analogous reactions of similar reagents.