Kinetic Study of Oxidation of L-Sorbose-by Thallic Perchlorate
| Main Authors: | A. G. FADNIS, S. K. SHRIVASTAVA |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1983
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6345704 |
Daftar Isi:
- Department of Chemistry, Govt. Science College, Gwalior Manuscript received 13 july 1981, revised 8 March 1982, accepted 10 December 1982 The oxidation of L-sorbose by thallic perchlorate has a first order dependence on TI(III) concentration. Variation of rate with L-sorbose is consistent with Michaelis-Menten kinetics. The rate is retarded by acidity, chloride and acetate ions, The thermodynamic parameters are reported. Suitable steps are proposed and rate law is given to explain the results obtained.