Metal Complexes with N'-Benzoyl-N2-(5-phenyl or 5-p .. anisyl-1 ,3, 4-oxadiazole-2-yl)thiocarbamide
| Main Authors: | K. C. SATPATHY, B. B. JAL, R. MISHRA, (Mrs.) S. PRADHAN |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1984
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6341238 |
Daftar Isi:
- P. G. Department of Chemistry, Sambalpur University, Jyoti Vihar, Burla-768 017 The thiourea derivatives N1-benzoyi-N2-(5-phenyl-1,3,4-oxadiazole-2-yl)thiocarbamide (BPODTC) and N1-benzoyl-N2(5-p-anisyl-1,3,4-oxadiazole-2-yl)thiocarbamide (BAODTC) are utilised for the preparation of CoII, NiIIand Cull complexes in ethanol medium. The structure of the complexes has been studied with the help of analytical and magnetic susceptibility data, uv and ir spectral measurements, conductometric and thermogravimetric analyses. The crystal field parameters of CoII and NiII are also calculated. BPODTC acts as a bidentate ligand whereas BAODTC a tridentate one. [M2(BAODTC)2X4 1 and [M(BPODTC)2X2. where M=CoII, CuII, X=CI-, Br- \(NO^-_{3}\) and \(CIO^-_{4}\); have octahedral and distorted octahedral configurations, respectively, whereas [Ni2 ( BAODTC)2 X4 ) is found to be octahedral and [Ni(BPODTC)2},X2. square planner in ~ature. low molar conductance values in acetone except that of [Ni(BPODTC)2]X. which is ionic, indicate that all these complexes are non-electrolytic.