Electrochemical Behaviour of N'-Benzoyl-3,5-diphenyl-4-(substituted-benzeneazo )pyrazoles
| Main Authors: | B. SATHYA SURYANARAYANA, P. VENKATA RAMANA, L. K. RAVINDRANATH, V. SESHAGIRI, S. BRAHMAJI RAO |
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| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1989
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6340133 |
Daftar Isi:
- Department of Chemistry, S. K. University, Anantapur-515 003 Manuscript received 20 February 1989, revised 6 June 1989, accepted 21 June 1989 The electrochemical behaviour of N'-benzoyl-3,5-diphenyl-4-(substituted-benzeneÂazo)pyrazoles are studied in Britton—Robinson buffers (pH-2.10-10.10) containing (0.0% (v/v) dimethylformamide, using polarographic, voltammetric and millicoulometric methods. All the compounds exhibited a well-defined 2-electron reduction wave at DME and a well-defined cathodic peak at HMDE. A plausible mechanism has been suggested on the basis of number of protons and electrons involved in the reduction process. The effect of organic co-solvent and double layer effect on the electrode process have been discussed.