On Variation of the Transference Number of an Ion of a Strong Electrolyte in Solution according to Cube-root of its Concentration
| Main Author: | B. N. GHOSH |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1986
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6256765 |
Daftar Isi:
- University College of Science and Technology, Calcutta-700 009 Manuscript received 3 April 2986, accepted 17 February 1986 In previous publications it has been shown on the basis of theoretical consideration that kappa of the Debye-Hὒckel theory of strong electrolytes requires modification. The expression for the modified kappa, km, deduced theoretically, includes within it 'the effective ionic diameter' a and varies according to cube-root of concentration of the electrolyte in solution so long as a (the effective ionic diameter) remains constant Equations for the cationic transference numbers of the strong electrolytes deduced by using the modified km have been subjected to test using the data available in the literature and have been found satisfactory.