Physicochemical Studies of 3d-Metal Complexes of Potassium Ethylene Dixanthate
| Main Authors: | RAJ KUMAR, M. N. ANSARI, M. C. JAIN, A.A. KHAN |
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| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1987
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6159316 |
Daftar Isi:
- Department of Chemistry, S. D. (P. G.) College, Muzaffarnagar-251 001 Department of Chemistry, Ali garb Muslim University, Aligarh-202 001 Manuscript received 12 March 1986, accepted 16 November 1986 Interaction of some 3d-metals with potassium ethylene dixanthate has been extensively studied by different physicochemical methods. Electrometric and chemical analysis gave 1 : 1 metal - ligand ratio. All the complexes are found to be paramagnetic showing magnate moment values corresponding to the spin values of unpaired electrons. All the xanthamto complexes are high-spin, having octahedral stereo-chemistry with sp2 d2 bridisation except Cu-complex which has square-planar geometry with dsp2 hybridisation. Infrared spectral data showed M-S bonding and coordinated water in all the complexes except copper complex where water is present as a water of crystallisation.