Diphenylthiovioluric Acid as a Sensitive and Selective Reagent for Extractive Spectrophotometric Determination of Palladium II
| Main Authors: | F. KAMIL, R. S. CHAWLA, S. K. SINDHWANI |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1988
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6090319 |
Daftar Isi:
- Department of Chemistry, University of Delhi, Delhi-110 007 Manuscript received 22 July 1980, revised 6 April 1988, accepted 17 August 1988 Diphenylthiovioluric acid has been used for the spectrophotometrie determination of palladium(II). The 1 : 2 (metal-ligand) complex exhibits maximum absorption at 425 nm. The system obeys Beer's law upto 4.96 ppm of Pd with sensitivity of 0.0035 \(\mu\)g Pd/cm2 for an absorbance of 0.001. The method has been proposed for the estimation of 7- 35 \\(\mu\)g Pd over the pH range 1.0- 3.5. The effcet of foreign lons has been studied and the determination has been carried out in synthetic mixtures.