Thallium(III) Acetate Oxidation of some Substituted-4-piperisones A Kinetic ans Mechanistic Study
| Main Authors: | (Mrs.) KR. MEENAL, (Mrs.) S. LALITHA |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1992
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6042813 |
Daftar Isi:
- Department of Chemistry. Seethalakshmi Ramaswamy College (Autonomous), Trichy-820 002 Manuscript received 24 December 1991, revised 8 July 1992, accepted 4 August 1992 Kinetics of oxidation of 2,6 diphenyl-4-piperldone, 3-alkyl and 3,5-dimethyl substituted 4 piperidones with TI II In aqueous acetic acid (80%,v v) in the presence of sulphuric acid (0 75 mol dm-2) at constant ionic strength (μ =2 25 M) over the temperature range 30- 55° have been investigated The reactions obey second order kinetics. Dependence on acidity is unity Added sodium sulphate does not have any effect. Activation parameters have been calculated and the structure-reactivity relationships discussed. A mechanism involving fast enolisation step is postulated.