Preparation and Spectroscopic Studies of Charge Transfer Complexes of Indolyldiene Aniline Derivatives with Di- and Tri-nitrobenzenes
| Main Authors: | H. A. DESSOUKI, M. GABER, R. M. ISSA, E. E. HOSSANI |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1988
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6024669 |
Daftar Isi:
- Chemistry Department, Faculty of Science, Benha University, Benha, A. R. Egypt Manuscript received 10December 1986, revised 28 October 1987, accepted 29 February 1988 The solid CT complexes of some indolyldiene aniline derivatives with di- and tri-nitrobenzenes have been prepared and investigated by ir, electronic and 1H nmr (DMSO d6.) spectroscopy. Non-acidic or weakly acidic acceptors yield complexes having π – π* and \( n\)-π* bonding. Strong acidic acceptors yield complexes having π – π* and proton transfer interaction. The formation of 1: 2 (D : A) complexes is also ascertained. The ionisation potential of the donors as well as the electron affinities of the acceptors are determined from the electronic absorption spectra