Studies on some Mixed-ligand Complexes of Cobalt(II), Nickel(II), Copper(II) and Zinc(II) with Pyridine-2-carboxylic Acid and Thiophene-2-carboxylic Acid

Main Authors: RAJESH NAGAR, R. C. SHARMA
Format: Article Journal
Bahasa: eng
Terbitan: , 1988
Subjects:
Online Access: https://zenodo.org/record/6024135
Daftar Isi:
  • Department of Chemistry, Agra University, Agra-282 010 Manuscript received 27 April 1987, revised 8 February 1988, accepted 19 February 1988 The formation of ternary metal(II)/thiophene-2-carboxylic acid/pyridine-2-carboxylic acid complexes with CoII, NiII, CuII and ZnII, has been studied potentiometrically at 25 and 40±1° and constant ionic strength (μ = 0.1 M KNO,) in aqueous solution. The stability order was found to be Cull > NiII > CoII > ZnII. pH-metric results were further supported by characterisation of some of the isolated complexes.