Kinetics and Mechanism of Oxidation of Selenium(IV) by Ditelluratoargentate(III)
| Main Authors: | N. SRIDEVI, R. RAMBABU, L. S. A. DIKSHITULU |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1992
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/5992456 |
Daftar Isi:
- Department of Inorganic and Analytical Chemistry, School of Chemistry, Andhra University, Visakhapatnam-530 003 Manuscript received 22 April 1991, revised 27 August 1991 accepted 5 March 1992 The title oxidation is first order each in oxidant, selenium(IV) and alakli and inverse first order in tellurium(VI). The rate of the reaction increases with increase in ionic strength. Ea and ΔS≠ values at 40° are found to be 23.3 ± 1.5 kJ mol-1 and 12.6 ± 4.8 JK-1 mol-1 respectively. A suitable mechanism is proposed.