A Study of Alkaline Hydrolysis of Methyl Nicotinate in Aquo-ethane-1 ,2-diol Solvent System
| Main Author: | L. N. SINHA |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1998
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/5936210 |
Daftar Isi:
- Department of Chemistry, Ranchi University, Ranchi-834 008 Manuscript received 9 January 1997, revised 16 March 1998, accepted 23 March 1998 Alkaline hydrolysis of methyl nicotinate has been studied in water-ethane-1,2-diol solvent system from compositions 0 to 50% (v/v) of etbane-1,2-diol at temperatures 20, 25,30 and 35°. The rates decrease with the increasing content of organic co-solvent at all the temperatures. The isocomposition activation energy and the thermodynamic activation parameters have been evaluated which show interesting behaviour with variations in the solvent composition.