A bimetallic dioxomolybdenum(VI) complex containing coordinated dihydrazone in staggered configuration
Main Authors: | Ram A. Lal, Arvind Kumar, Jayanta Chakraborty |
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Format: | Article Journal |
Bahasa: | eng |
Terbitan: |
, 2001
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Subjects: | |
Online Access: |
https://zenodo.org/record/5872906 |
Daftar Isi:
- Department of Chemistry, Tripura University, Agartala-799 004, India E-mail : ralal_tu@yahoo.com Manuscript received 28 October 1999. revised 29 November 2000. accepted 24 February 2001 The reaction between bis(acctylacetonato)dioxomolybdenum(VI) and bis(2-hydroxy-1-naphthaldehyde)malonoyldihydrazone yields homobimctallic complex [(MoO2)2(CH2L)(H2O)2] in which dihydrazonc coordinates to the metal centres in the staggered configuration. The complex undergoes a dynamic process in solution in which the dissociated form remain in equilibrium with the undissociated form.