Synthesis and characterisation of 8-aminoquinoline complexes of platinum(II) and palladium(II). Kinetics of dimethyl sulphoxide entry into the coordination sphere
| Main Authors: | Monojit Ray, Santanu Bhattacharya, Pradyot Banerjee |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1999
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/5853132 |
Daftar Isi:
- Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta-700 032, India Manuscript received 30 October 1998, accepted 16 November 1998 The synthcsis and characterisation of 8-aminoquinoline (8-AMQ) complexes of platinum(n) and palladium(n) have been reported. Kinetic study of dimethyl sulfoxide (DMSO) entry into the coordination sphere of Pt(8-AMQ)Cl2 and Pd(8-AMQ)Cl2 has been undertaken through spectrophotometric measurements showing the replacement of one Cl- from the complexes. 1H nmr studies support the S-bonding to the metal centre in the DMSO substituted species