Kinetics of cationic micelle catalyzed oxidation of cyclohexanone by vanadium(v)
| Main Authors: | Jagannath Panda, G. P. Panigrahi |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 2002
|
| Subjects: | |
| Online Access: |
https://zenodo.org/record/5840274 |
Daftar Isi:
- Department of Chemistry, Berhampur University, Berhampur-760 007, India E-mail : ganesh_panigrahi@yahoo.com Manuscript received 22 December 2000, revised 16 March 2001, accepted 31 May 2001 Oxidation of cyclohexanone by vanadium(v) in sulfuric acid medium is catalyzed marginally in presence of CTAB and NDPC, reaches a maximum and then decreases. The oxidation rate-[micelle] profile is rationalized by Berezin model and binding constants of both the reactants with the micelle have been computed using the model. The data also fit into Piszkiewicz model.