Static dielectric constant of some pure protic and aprotic solvents and for binary solvent mixtures
| Main Authors: | A. Guha, Rupa Pal |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 2006
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/5816419 |
Daftar Isi:
- Department of Chemistry, University of Kalyani, Kalyani-741 235. Nadia. West Bengal. India E-mail : drasit_guha@yahoo.co. in B. P. Poddar Institute of Management & Technology, Kolkata-700 052, India E-mail : drumil_rupa @yahoo.co.uk Manuscript received 6 December 2004, revised 21 September 2005, accepted 23 September 2005 The dielectric constant values of some protic and aprolic solvents in pure state are presented on the basis of MSA method, perturbation theoQ and Cluster expansion formulation. The calculations are made on statistical mechanical basis considering the cooperative effect and formation of cluster by H-bonding or dipole alignment. The results are compared with the experimental values. To calculate this for binary mixtures of some important mixed solvents we have to consider the partial molar volumes, which arc calculated from a relation considering the hard sphere diameters and number density of the corresponding solvents. The results are compared with the experimental values and this agreement is found good.