Spectroscopic studies of some VOII complexes
| Main Authors: | Rajeev Ranjan, Rekha Rani, Vijay Kumar, A. K. Singh (Jr.), S. Sharma |
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| Format: | Article |
| Bahasa: | eng |
| Terbitan: |
, 2008
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/5814521 |
Daftar Isi:
- University Department of Chemistry, Magadh University, Bodh Gaya-824 234, Bihar, India E-mail: shivadharmuchem@yahoo.com.in Manuscript received 11 April 2007, revised 14 November 2007, accepted 26 November 2007 The reaction of 2-formylpyridine semicarbazone (HFPS), 2-formylpyrldlne thiosemicarhazone (HFPTS), 2- acetylpyridine semicarbazone (HAPS) and 2-acetylpyridine thiosemicarbazone (HAPTS) with VOSO4 In ethanolic solution affords the complexes of formula VOL2, where L = FPS, APS, FPTS and APTS. The Infrared spectra of complexes in comparison to that of the free ligand show the mode of coordination of the ligands. The appearance of three bands in their electronic spectra is indicative of their square pyramidal geometry which is further substantiated by their electron spin resonance spectra. The presence of eight lines in the hyperfine ESR spectra shows that they are mononuclear complexes.