Trinuclear complexes of alkali metals with anhydrous nickel salicylate and copper salicylate
| Main Authors: | Sheo Satya Prakash, Deepa Bariar, J. Kumar, Manilal, Syed Khalid Mustafa, Nilima Dhar |
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| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 2008
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/5808891 |
Daftar Isi:
- P.G. Department of Chemistry, A. N. College, Patna-800 013, Bihar, India Oriental College, Patna City, Bihar, India Department of Chemistry, J. D. Women's College, Patna, Bihar, India Manuscript received 19 November 2007, accepted 23 November 2007 Ni(HSal)2 and Cu(HSal)2 complexes have been used as ligands in the synthesis of trinuclear alkali metal complexes having general formula [Ma(HL)2 .2MbL], where Ma = CuII or NiII; HL = salicylic acid, Mb = Li+, Na+ and K+; L = α-nitroso-β-naphthol (1N2N), 8-hydroxyquinoline (8HQ), NaSCN and KBr. These trinuclear complexes are considerably less soluble in ethanol than the complex ligand. Magnetic spectral and infrared spectral data suggest that they are oxygen bridged trinuclear complexes.