Synthesis, characterization and X-ray structure of a mononuclear mercury(n) thiocyanato complex containing a tripodal amine
| Main Authors: | Soumi Chattopadhyay, Sumitava Khan, Subhasish Kundu, Kishalay Bhar, Rajarshi Ghosh, Barindra Kumar Ghosh |
|---|---|
| Format: | Article |
| Bahasa: | eng |
| Terbitan: |
, 2013
|
| Subjects: | |
| Online Access: |
https://zenodo.org/record/5764069 |
Daftar Isi:
- Department of Chemistry, The University of Burdwan, Burdwan-713 104, West Bengal, India E-mail : barin_1@yahoo.co.uk Fax : 91-342-2530452 Manuscript received online 15 March 2012, revised 05 April 2012, accepted 11 April 2012 Mononuclear compound of the type [Hg(tren)(SCN)]CI04 (1) [tren = tris(2-aminoethyl)amine] has been isolated and characterized with the help of microanalytical, spectroscopic and single crystal X-ray diffraction studies. Mercury(II) center in 1 adopts a distorted trigonal bipyramidal geometry with an HgN4S chromophore. Primary N atoms of tren constitute the basal plane, and remaining tertiary amine N atom and S atom of terminal thiocyanate are in the apical positions. In the crystalline state, complexed cations and counter anions are engaged in N-H...N, N-H...O, N-H...S and C-H...N hydrogen bonds resulting in a 3D network structure.