Use of agro-industrial residues of plantain (Musa paradisiaca) in the adsorption of Ni (II)

Main Authors: Candelaria Tejada-Tovar, Ángel Villabona-Ortíz, Walter Cortina-Góngora, Betty Díaz-Navarro, Rodrigo Ortega Toro
Other Authors: Revista Facultad de Ingeniería, Universidad de Antioquia
Format: Article Journal
Bahasa: eng
Terbitan: , 2021
Subjects:
Online Access: https://zenodo.org/record/5739362
Daftar Isi:
  • The presence of heavy metals in aqueous media represents a severe threat to ecosystems because they are non-biodegradable, toxic, and carcinogenic. In the present work, the utilization of agro-industrial residues from obtaining plantain starch for removing Ni (II) was studied, establishing the effect of temperature, adsorption dose, and initial concentration. The kinetics, equilibrium, and thermodynamic parameters that determine the process were studied. For this purpose, tests were carried out in a batch system maintaining constant stirring (200 rpm), pH (2), and solution volume (100 mL). The remaining metal concentration was determined by atomic adsorption at 237 nm. It was found that the best adsorption conditions were given at 55 oC, 0.6775 g, and 368 mg/L obtaining a maximum adsorption capacity of 47.57 mg/g corresponding to a removal of 87%. The kinetic model that best fits the experimental data was a pseudo-second-order model, and the isotherm that describes the process is Langmuir and Freundlich, so the adsorption is given by chemisorption and multilayers. The thermodynamic parameters determined suggest that the process is favourable, not spontaneous, endothermic, and irreversible under the studied conditions. The results show that the residual biomass from the obtaining of plantain starch is a good precursor for absorbing Ni (II) in an aqueous solution