Synthesis and physicochemical studies of cobalt(II), nickel(II) and copper(II) complexes with various Schiff bases containing oxygen and nitrogen donor atoms
| Main Authors: | Raj Kumar Dubey, Sharad Kumar Mishra, Ashok Kumar Jha, Manoj Kumar |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 2018
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/5642780 |
Daftar Isi:
- Synthetic Inorganic and Metallo-Organic Research Laboratory, Department of Chemistry, University of Allahabad, Allahabad-211 002, Uttar Pradesh, India E-mail: rajalkoxy@yahoo.com Department of Chemistry, G. B. College, T. M. Bhagalpur University, Naugachia-853 204, Bihar, India Manuscript received 07 April 2017, revised 02 May 2018, accepted 03 May 2018 The complexes of cobalt(II), nickel(II) and copper(II) of the types [(sb)2M.2H2O] [where M = CoII, NiII and CuII], [sbH = sapH, napH], [(Cl)Cu(sb)] and [Cu(sb)2] [sb = sapH, smabH] have been prepared by using simple metathetic reactions. The structural characterization of the complexes, synthesized during the present course of investigations have been elucidated by elemental analysis (C, H, N, Cl and Cu), IR, electronic spectral data, ESR, FAB-MS and magnetic studies. Thermogravimetric studies have also been carried out for some of the hydrated metal complexes.