Extraction studies of ZnII from salicylate medium using Cyanex-923 extractant in toluene
| Main Authors: | S. U. Gaikwad, S. D. Pawar |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 2015
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/5602975 |
Daftar Isi:
- Department of Chemistry, University of Mumbai, Lokmanya Tilak Bhavan, Vidyanagari, Santacruz (E), Mumbai-400 098, India E-mail : sureshpawar2004@gmail.com Fax : 91-22-26528547 Manuscript received online 29 May 2014, revised 04 August 2014, accepted 07 August 2014 Cyanex-923 extractant has been used for the extraction of ZnII from sodium salicylate medium. This metal ion was quantitatively extracted with Cyanex-923 in toluene at pH 5 and from the organic phase it is stripped back with 1 M HCl solution. The effect of pH, sodium salicylate concentration, reagent concentration, equilibration period, diluents, diverse ions and stripping agent on the extraction of ZnII has been studied. The stoichiometry of the extracted species was determined on the basis of slope analysis method. The extraction proceed by solvation mechanism and the probable extracted species was Zn(HSal)2 .2Cyanex-923.